Edoardo has chosen Cricket Brings Hope, a charity using the sport to channel positive social change in Rwanda, for guests to learn more about.
Princess Beatrice and her fiancé were engaged last September, with the groom popping the question when they were in Italy.
It was announced last month the ceremony would not be televised despite Prince Harry, Prince William, 37, and sister Princess Eugenie, 29, sharing their wedding day with the British public.
ITV and BBC both confirmed they would not be filming coverage of the ceremony at the start of the year.
This Morning airs weekdays at 10am on ITV.